you have this bit in your window.mxml code:
<mx:Image source="{selectedImage}"/>
but you probably need to set that property when you pop the window open:
Code:
private function launchPopUp(e:MouseEvent):void {
if(images.selectedImage){
var win : Window = new Window();
win.selectedImage = images.selectedImage; //set it here...
PopUpManager.addPopUp(win,this,true);
PopUpManager.centerPopUp(win);
}